It is recommended to pray Subh when it is still dark on the day of sacrifice in Al-Muzdalifah, and to do it very early after ascertaining that dawn has broken

A'bdullah (b. 'Umar) reported:

I have never seen Allah's Messenger (ﷺ) , (ﷺ) but observing the prayers at their appointed times except two prayers, sunset and 'Isha, ' at Muzdalifa (where he deferred the sunset prayer to combine it with 'Isha' and he observed the dawn prayer before its stipulated time on that day (10th of Dhu'l-Hijja).

حَدَّثَنَا يَحْيَى بْنُ يَحْيَى، وَأَبُو بَكْرِ بْنُ أَبِي شَيْبَةَ وَأَبُو كُرَيْبٍ جَمِيعًا عَنْ أَبِي مُعَاوِيَةَ، - قَالَ يَحْيَى أَخْبَرَنَا أَبُو مُعَاوِيَةَ، - عَنِ الأَعْمَشِ، عَنْ عُمَارَةَ، عَنْ عَبْدِ الرَّحْمَنِ بْنِ يَزِيدَ، عَنْ عَبْدِ اللَّهِ، قَالَ مَا رَأَيْتُ رَسُولَ اللَّهِ صلى الله عليه وسلم صَلَّى صَلاَةً إِلاَّ لِمِيقَاتِهَا إِلاَّ صَلاَتَيْنِ صَلاَةَ الْمَغْرِبِ وَالْعِشَاءِ بِجَمْعٍ وَصَلَّى الْفَجْرَ يَوْمَئِذٍ قَبْلَ مِيقَاتِهَا ‏.‏

This hadith has been transmitted by Al-A`mash with a slight variation of words, i.e. he said before its time when it was still dark.

وَحَدَّثَنَا عُثْمَانُ بْنُ أَبِي شَيْبَةَ، وَإِسْحَاقُ بْنُ إِبْرَاهِيمَ، جَمِيعًا عَنْ جَرِيرٍ، عَنِ الأَعْمَشِ، بِهَذَا الإِسْنَادِ وَقَالَ قَبْلَ وَقْتِهَا بِغَلَسٍ ‏.‏